Chemistry Lab Protocols / Fundamental laboratory techniques
Choosing between glass and plastic containers
Bear in mind the following points:
- Reactivity: Plastic vessels often distort at relatively low temperature, may
be inflammable, may dissolve in certain organic solvents and may be
affected by prolonged exposure to ultraviolet (UV) light.
- Opacity: Both glass and plastic absorb light in the UV range of the
electromagnetic spectrum (Table 3.2). Quartz should be used where this is
important, e.g. in cells for UV spectrophotometry or
photochemistry.
- Contamination: Some plasticizers may leach from vessels, especially with
some organic solvents, such as DCM. Glass may adsorb ions and other
molecules and then leach them into solutions, especially under acidic or
alkaline conditions. Pyrex® glass is stronger than ordinary soda glass
(rarely found except in specific items such as Pasteur pipettes and melting
point tubes, but check if you are not sure) and can withstand
temperatures up to 500°C.
- Rigidity and resilience: Plastic vessels are not recommended where
volume is critical as they may distort through time. Glass vessels are more
easily broken than plastic.
- Disposability: Plastic items may be cheap enough to make them
disposable, an advantage where there is a risk of chemical contamination.
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